Abstract
The title compound, C12H14N2O3S, crystallizes with two independent molecules (A and B) in the asymmetric unit. The five-membered imidazolidin-2-one rings in both molecules are twisted about the C-C bond. In the crystal, the A and B molecules are associated via pairs of N-H center dot center dot center dot O hydrogen bonds, forming A-B dimers. These dimers are linked via C-H center dot center dot center dot S hydrogen bonds, forming double dimers, which are in turn linked via C-H center dot center dot center dot O hydrogen bonds forming two-dimensional networks lying parallel to (001). There are also C-H center dot center dot center dot pi interactions present, which consolide the layers and link them, so forming a three-dimensional structure.