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1-butyl-3-methylimidazolium 3,5-dinitro-1,2,4-triazolate: a novel ionic liquid containing a rigid, planar energetic anion
Journal article   Peer reviewed

1-butyl-3-methylimidazolium 3,5-dinitro-1,2,4-triazolate: a novel ionic liquid containing a rigid, planar energetic anion

Alan R Katritzky, Shailendra Singh, Kostyantyn Kirichenko, John D Holbrey, Marcin Smiglak, W Matthew Reichert and Robin D Rogers
Chemical communications (Cambridge, England), (7), pp.868-870
21/02/2005
PMID: 15700064

Abstract

The novel ionic liquid, 1-butyl-3-methylimidazolium 3,5-dinitro-1,2,4-triazolate has been synthesized and exhibits an unexpectedly low melting point (35 degrees C) considering the size and shape of the rigid, planar anion; analogous tetraalkylammonium salts (methyl, ethyl and n-butyl) have also been prepared and the tetraethylammonium example was characterized by single crystal X-ray diffraction.

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