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1,3-DIPOLAR CYCLOADDITION OF DIAZOALKANES WITH MONOSUBSTITUTED ALKENES AND A,B-UNSATURATED ENONES AND EVALUATION OF THEIR ANTITUBERCULAR ACTIVITY
Journal article

1,3-DIPOLAR CYCLOADDITION OF DIAZOALKANES WITH MONOSUBSTITUTED ALKENES AND A,B-UNSATURATED ENONES AND EVALUATION OF THEIR ANTITUBERCULAR ACTIVITY

Khaoula Hajlaoui, Ahlem Guesmi, Naoufel Ben Hamadi and Moncef Msaddek
Heterocyclic letters, Vol.10(2), pp.205-211
01/02/2020

Abstract

Chemistry Chemistry, Organic Physical Sciences Science & Technology
The regiospecific synthesis of pyrazolines has been accomplished through the 1,3-dipolar cycloaddition of diazoalkanes. The reaction of 2-diazopropane 1 with monosubstituted alkenes 2 has been studied. It led to pyrazolines derivatives 3. In addition the reactivity of p-toluldiazomethane 4 towards alpha,beta-unsaturated enones 5 is reported, affording Delta(2)-pyrazolines. Products were screened for their antimycobacterial activity against Mycobacterium tuberculosis H37Rv strain.

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