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1D silver cluster-assembled materials act as a platform for selectively erasable photoluminescent switch of acetonitrile
Journal article   Peer reviewed

1D silver cluster-assembled materials act as a platform for selectively erasable photoluminescent switch of acetonitrile

Ya-Hui Li, Ren-Wu Huang, Peng Luo, Man Cao, Hong Xu, Shuang-Quan Zang and Thomas C. W. Mak
Science China. Chemistry, Vol.62(3), pp.331-335
01/03/2019
DOI: https://doi.org/10.1007/s11426-018-9387-7

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
A new 1D silver cluster-assembled complex Ag(10)bpy-CH3CN exhibiting intense photoluminescence was reported. Upon the loss of coordinated acetonitrile, Ag(10)bpy-CH3CN form Ag(10)bpy with Ag10S6 cores slightly distorted, being accompanied with photoluminescence quenching. Inverse process can be realized by treating Ag(10)bpy with acetonitrile and shows a selectively erasable photoluminescent switch.

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