Abstract
The title compound, C19H23N3S, is a functionalized triazoline3-thione derivative. The benzyl ring is almost normal to the planar 1,2,4-triazole ring (r.m.s. deviation = 0.007 angstrom) with a dihedral angle of 86.90 (7)degrees. In the crystal, molecules are linked by pairs of N-H center dot center dot center dot S hydrogen bonds, forming inversion dimers that enclose R-2(2) (8) loops. The crystal packing is further stabilized by weak C-H center dot center dot center dot pi interactions that link adjacent dimeric units into supramolecular chains extending along the a- axis direction.