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4-Connected metal-organic assemblies mediated via heterochelation and bridging of single metal ions: Kagome lattice and the M6L12 octahedron
Journal article   Peer reviewed

4-Connected metal-organic assemblies mediated via heterochelation and bridging of single metal ions: Kagome lattice and the M6L12 octahedron

Yunling Liu, Victor Ch Kravtsov, Derek A Beauchamp, Jarrod F Eubank and Mohamed Eddaoudi
Journal of the American Chemical Society, Vol.127(20), pp.7266-7267
25/05/2005
DOI: https://doi.org/10.1021/ja051259q
PMID: 15898747

Abstract

Single-metal-ion-based rigid molecular building blocks (MBBs) have been utilized to design and synthesize novel metal-organic assemblies. Reaction between In(NO3)3.2H2O and 2,5-pyridinedicarboxylic acid (2,5-H2PDC) has permitted the assembly of two supramolecular isomers, a Kagomé lattice and an unprecedented M6L12 discrete octahedron.

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