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A [NiFe]hydrogenase model that catalyses the release of hydrogen from formic acid
Journal article   Peer reviewed

A [NiFe]hydrogenase model that catalyses the release of hydrogen from formic acid

Nga T. Nguyen, Yuki Mori, Takahiro Matsumoto, Takeshi Yatabe, Ryota Kabe, Hidetaka Nakai, Ki-Seok Yoon, Seiji Ogo and Patrik Schmuki
Chemical communications (Cambridge, England), Vol.50(87), pp.13385-13387
11/11/2014
DOI: https://doi.org/10.1039/c4cc05911e
PMID: 25019463

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
We report the decomposition of formic acid to hydrogen and carbon dioxide, catalysed by a NiRu complex originally developed as a [NiFe]hydrogenase model. This is the first example of H-2 evolution, catalysed by a [NiFe]hydrogenase model, which does not require additional energy.

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