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A Novel [OSSO]-Type Chromium(III) Complex as a Versatile Catalyst for Copolymerization of Carbon Dioxide with Epoxides
Journal article   Peer reviewed

A Novel [OSSO]-Type Chromium(III) Complex as a Versatile Catalyst for Copolymerization of Carbon Dioxide with Epoxides

Francesco Della Monica, Veronica Paradiso, Alfonso Grassi, Stefano Milione, Luigi Cavallo and Carmine Capacchione
Chemistry : a European journal, Vol.26(24), pp.5347-5353
24/04/2020
DOI: https://doi.org/10.1002/chem.201905455
PMID: 31999359

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
A new chromium(III) complex, bearing a bis-thioether-diphenolate [OSSO]-type ligand, was found to be an efficient catalyst in the copolymerization of CO2 and epoxides to achieve poly(propylene carbonate), poly(cyclohexene carbonate), poly(hexene carbonate) and poly(styrene carbonate), as well as poly(propylene carbonate)(cyclohexene carbonate) and poly(propylene carbonate)(hexene carbonate) terpolymers.

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