A Novel heteroleptic paddlewheel diruthenium bicyclic guanidinate complex: Synthesis, structure, and scope

Richmond Lee; Yuanyong Yang; Geok Kheng Tan; Choon-Hong Tan; Kuo-Wei Huang

doi:10.1039/b915881b

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A Novel heteroleptic paddlewheel diruthenium bicyclic guanidinate complex: Synthesis, structure, and scope

Journal article

Peer reviewed

A Novel heteroleptic paddlewheel diruthenium bicyclic guanidinate complex: Synthesis, structure, and scope

Richmond Lee, Yuanyong Yang, Geok Kheng Tan, Choon-Hong Tan and Kuo-Wei Huang

Dalton transactions : an international journal of inorganic chemistry, Vol.39(3), pp.723-725

01/01/2010

DOI: https://doi.org/10.1039/b915881b

PMID: 20066216

Abstract

Chemistry

Chemistry, Inorganic & Nuclear

Physical Sciences

Science & Technology

A novel paddlewheel or 'lantern' heteroleptic diruthenium guanidinate complex Ru-2(TBO)(2)(OAc)(2)Cl center dot 3MeCN (1 center dot 3MeCN) was synthesized and structurally characterized. Compared with a known tetra-substituted di-ruthenium guanidinate complex Ru-2(TBD)(4)Cl, 1 revealed structural dissimilarities with internal twisting.

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Title: A Novel heteroleptic paddlewheel diruthenium bicyclic guanidinate complex: Synthesis, structure, and scope
Creators - without role: Richmond Lee - National University of Singapore
Yuanyong Yang - National University of Singapore
Geok Kheng Tan - National University of Singapore
Choon-Hong Tan - National University of Singapore
Kuo-Wei Huang - National University of Singapore
Publication Details: Dalton transactions : an international journal of inorganic chemistry, Vol.39(3), pp.723-725
Publisher: Royal Soc Chemistry
Number of pages: 3
Grant note: R143-000-346-133; R-143-000-376-112; R-143-000-337-112; R-143-000-342-112 / National University of Singapore
Identifiers: 9942979108331
Academic Unit: King Abdullah University of Science & Technology
Language: English
Resource Type: Journal article