Sign in
Back
A Rare mu(4)-O Centred Dy-4 Tetrahedron with Coordination-Induced Local Chirality and Single-Molecule Magnet Behaviour
Journal article   Peer reviewed

A Rare mu(4)-O Centred Dy-4 Tetrahedron with Coordination-Induced Local Chirality and Single-Molecule Magnet Behaviour

Po-Heng Lin, Ilia Korobkov, Wolfgang Wernsdorfer, Liviu Ungur, Liviu F. Chibotaru and Muralee Murugesu
European journal of inorganic chemistry, Vol.2011(10), pp.1535-1539
01/04/2011
DOI: https://doi.org/10.1002/ejic.201100038

Abstract

Chemistry Chemistry, Inorganic & Nuclear Physical Sciences Science & Technology
Coordination-induced chirality was achieved in a unique tetrahedral [Dy-4(mu(4)-O)(mu-OMe)(2)(beh)(2)(esh)(4)]center dot 3MeOH complex through a twisted diazine bridge from a Schiff base ligand. Magnetic measurements reveal weak intramolecular antiferromagnetic interactions (J = -0.3 cm(-1)) with single-molecule magnet behaviour (U-eff = 23.42 K).

Metrics

1 Record Views

Details