Abstract
Aqueous ammonium ion battery is a promising sustainable energy storage system. However, the side reactions originating from electrolytes (the water decomposition and host material dissolution) preclude its practical applications. Unlike the metal-based aqueous batteries, the idea of “ultrahigh concentrated electrolyte” is not feasible due to the strong hydrolysis of ammonium ions. Therefore, we proposed an effective and sustainable strategy for the water hydrogen bond network modulation by adding sucrose into the electrolytes. The sucrose can form sucrose-water hydrogen bond networks to break the continuous water hydrogen bond network, thereby inhibiting water decomposition significantly. Moreover, the weak hydrogen bond interaction between ammonium and sucrose facilitates rapid ion migration, leading to an improved ionic conductivity. This work presents a new electrolyte modulating strategy for the practical application of aqueous ammonium ion batteries.
Research reported in this manuscript was funded by King Abdullah University of Science and Technology (KAUST) under competitive research grant number OSR-CRG2017-3379.J.Y. acknowledges financial support from the HongKong Polytechnic University (grant P0042930).