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A hydrogen bond scaffold supported synthetic heme Fe-III-O-2(-) adduct
Journal article   Peer reviewed

A hydrogen bond scaffold supported synthetic heme Fe-III-O-2(-) adduct

Kaustuv Mittra, Sudipta Chatterjee, Subhra Samanta, Kushal Sengupta, Hridaynath Bhattacharjee and Abhishek Dey
Chemical communications (Cambridge, England), Vol.48(85), pp.10535-10537
01/01/2012
PMID: 22992672

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
A hydrogen bonded heme-Fe-III-O-2(-) adduct is stabilized and characterized using resonance Raman and EPR spectroscopy. The low O-O vibrations of this complex are quite different from those reported for other heme-Fe-III-O-2(-) adducts.

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