A multi-metal-cluster MOF with Cu4I4 and Cu6S6 as functional groups exhibiting dual emission with both thermochromic and near-IR character

Xiao-chen Shan; Fei-long Jiang; Da-qiang Yuan; Hua-bin Zhang; Ming-yan Wu; Lian Chen; Jing Wei; Shu-quan Zhang; Jie Pan; Mao-chun Hong

doi:10.1039/c3sc21995j

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A multi-metal-cluster MOF with Cu4I4 and Cu6S6 as functional groups exhibiting dual emission with both thermochromic and near-IR character

Journal article

Peer reviewed

A multi-metal-cluster MOF with Cu4I4 and Cu6S6 as functional groups exhibiting dual emission with both thermochromic and near-IR character

Xiao-chen Shan, Fei-long Jiang, Da-qiang Yuan, Hua-bin Zhang, Ming-yan Wu, Lian Chen, Jing Wei, Shu-quan Zhang, Jie Pan and Mao-chun Hong

Chemical science (Cambridge), Vol.4(4), pp.1484-1489

01/01/2013

DOI: https://doi.org/10.1039/c3sc21995j

Abstract

Chemistry

Chemistry, Multidisciplinary

Physical Sciences

Science & Technology

Two classical metal clusters, (Cu4I4)-I-I and (Cu6S6)-S-I, are introduced as functional connecting nodes to construct a novel multi-metal-cluster MOF [((Cu4I4)-I-I)(3)(Cu-6(I))(2)(3-ptt)(12)](n)center dot 24nDEF center dot 12nH(2)O (1) that incorporate their inherent luminescent properties, induced by their respective metal-metal interactions. These two distinct clusters are combined together for the first time to perform as functional luminophores that display unusual dual emission with both thermochromic luminescence and near-infrared (NIR) character.

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Title: A multi-metal-cluster MOF with Cu4I4 and Cu6S6 as functional groups exhibiting dual emission with both thermochromic and near-IR character
Creators - without role: Xiao-chen Shan - Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
Fei-long Jiang - Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
Da-qiang Yuan - Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
Hua-bin Zhang - Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
Ming-yan Wu - Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
Lian Chen - Fujian Institute of Research on the Structure of Matter
Jing Wei - Fujian Institute of Research on the Structure of Matter
Shu-quan Zhang - Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
Jie Pan - Fujian Institute of Research on the Structure of Matter
Mao-chun Hong - Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
Publication Details: Chemical science (Cambridge), Vol.4(4), pp.1484-1489
Publisher: Royal Soc Chemistry
Number of pages: 6
Grant note: KJCX2-EW-H01 / Knowledge Innovation Program of the Chinese Academy of Sciences; Chinese Academy of Sciences 2011CBA00507; 2011CB932504 / 973 Program; National Basic Research Program of China NSF of Fujian Province; Natural Science Foundation of Fujian Province 21131006 / National Nature Science Foundation of China; National Natural Science Foundation of China (NSFC)
Identifiers: 9941904808331
Academic Unit: King Abdullah University of Science & Technology
Language: English
Resource Type: Journal article