A new 2D honeycomb-like cluster polymer built by a {Mn6Na3} cluster: Synthesis and magnetic property

Yun-En Xie; Chong-Bing Tian; Hua-Bin Zhang; Yan Peng; Xian-Qiang Li; Zhi-Hua Li; Ping Lin; Shao-Wu Du

doi:10.1016/j.inoche.2011.10.023

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A new 2D honeycomb-like cluster polymer built by a {Mn6Na3} cluster: Synthesis and magnetic property

Journal article

Peer reviewed

A new 2D honeycomb-like cluster polymer built by a {Mn6Na3} cluster: Synthesis and magnetic property

Yun-En Xie, Chong-Bing Tian, Hua-Bin Zhang, Yan Peng, Xian-Qiang Li, Zhi-Hua Li, Ping Lin and Shao-Wu Du

Inorganic chemistry communications, Vol.15, pp.198-201

01/01/2012

DOI: https://doi.org/10.1016/j.inoche.2011.10.023

Abstract

Chemistry

Chemistry, Inorganic & Nuclear

Physical Sciences

Science & Technology

A new 2D polymer, {[Mn6Na3(mu(6)-O)(thme)(4)(PhCO2)(6)(mu-H2O)(3)][OH]}(n) (1), has been synthesized and characterized by single crystal X-ray diffraction, XRD, IR spectroscopy, thermogravimetric analysis (TGA) and magnetic measurements. Compound 1 has a 2D honeycomb-like structure constructed by heterometallic {Mn6Na3} clusters, which are linked by water molecules cross-bridged between the Na (I) ions of the adjacent clusters. Magnetic property study reveals the existence of antiferromagnetic couplings between Mn (III) ions within the (Mn6Na3) clusters. (C) 2011 Elsevier B.V. All rights reserved.

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Title: A new 2D honeycomb-like cluster polymer built by a {Mn6Na3} cluster: Synthesis and magnetic property
Creators - without role: Yun-En Xie - Fujian Institute of Research on the Structure of Matter
Chong-Bing Tian - Fujian Institute of Research on the Structure of Matter
Hua-Bin Zhang - Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
Yan Peng - Fujian Institute of Research on the Structure of Matter
Xian-Qiang Li - Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
Zhi-Hua Li - Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
Ping Lin - Fujian Institute of Research on the Structure of Matter
Shao-Wu Du - Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
Publication Details: Inorganic chemistry communications, Vol.15, pp.198-201
Publisher: Elsevier
Number of pages: 4
Grant note: 2011KL007 / Key laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Chinese Academy of Sciences 2012CB821702 / National Basic Research Program of China (973 Program); National Basic Research Program of China State Key Laboratory of Structural Chemistry 20733003; 20903096 / National Natural Science Foundation of China; National Natural Science Foundation of China (NSFC) Institute of Research on the Structure of Matter
Identifiers: 9943463508331
Academic Unit: King Abdullah University of Science & Technology
Language: English
Resource Type: Journal article