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A new approach to the stereoselective carbodiazenylation of olefins by macrocyclization
Journal article   Peer reviewed

A new approach to the stereoselective carbodiazenylation of olefins by macrocyclization

Markus R. Heinrich, Olga Blank and Alexander Wetzel
Synlett, Vol.2006(19), pp.3352-3354
01/12/2006

Abstract

Chemistry Chemistry, Organic Physical Sciences Science & Technology
The reduction of bisaryldiazonium salts in the presence of olefins leads to macrocyclic azo compounds. Chiral auxiliaries incorporated in the bisaryldiazonium salt allow the stereochemical control of the newly formed carbon center.

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