Sign in
Back
A novel high-spin tridecanuclear Ni-II cluster with an azido-bridged core exhibiting disk-like topology
Journal article   Peer reviewed

A novel high-spin tridecanuclear Ni-II cluster with an azido-bridged core exhibiting disk-like topology

Gabriel Brunet, Fatemah Habib, Cyril Cook, Thushan Pathmalingam, Francis Loiseau, Ilia Korobkov, Tara J. Burchell, Andre M. Beauchemin and Muralee Murugesu
Chemical communications (Cambridge, England), Vol.48(9), pp.1287-1289
01/01/2012
DOI: https://doi.org/10.1039/c2cc16221k
PMID: 22179326

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
A high-spin tridecanuclear Ni-II cluster, [Ni-II (13)(N-3)(18)(dpo)(4)(Hdpo)(2)(H(2)hpo)(4)(H2O)(MeOH)] [Ni-II (13)(N-3)(18)(dpo)(4)(Hdpo)(2)(H(2)hpo)(4)(H2O)(2)] (1) (Hdpo = 1-(dimethylamino) propan-2-one oxime and H(2)hpo = 1-(hydroxyamino) propan-2-one oxime) with a purely azido-bridged core, is reported with dominant ferromagnetic coupling between Ni-II ions. The latter molecule exhibits a unique planar core topology with the largest N-3 : Ni-II ratio reported to date.

Metrics

1 Record Views

Details