Abstract
In this work, a novel optical fluoro-chemisensor was designed and synthesized for copper (II) ions detection. The sensor film is created by embedded N,N-Bis(2-hydroxo-5-bromobenzyl)ethylenediamine in poly vinyl chloride (PVC) film in presence of dioctyl phthalate (DOP) as plasticizer. The receptor Schiff base reveals “off-on” mode with high selectivity, significant sensitivity to Cu(II) ions. The selectivity of optical sensor for Cu(II) ions is the result of chelation enhanced fluorescence (CHEF). The optimal conditions of pH and response time at which higher efficiency of sensor film is performed was found to be 6.8 and 2.48min. The possible interference of other metal ions in solution was examined in presence of different types of metal ions. This film shows high selectivity and ultra-sensitivity with low detection limit LOD (1.1×10−8M). Thus, these considerable properties make it viable to monitor copper metal ions within very low concentration range (0–15×10−6M Cu(II)) and highly selective even in the presence of different types of metal ions. The sensor reversibility was achieved by utilizing EDTA solution with concentration of 0.1M solution.
A novel optical fluoro-chemisensor was designed and synthesized for copper (II) ions detection. The sensor film is created based on the embedded of N,N-Bis(2-hydroxo-5-bromobenzyl)ethylenediamine in poly-vinyl chloride (PVC) matrix. The optimal conditions of pH and response time at which higher efficiency of sensor film is performed were found to be 6.8 and 2.48min respectively. This film shows high selectivity and ultra-sensitivity with low detection limit of 7.6nM. [Display omitted]
•New chemi-sensor film based Schiff base for Cu(II) detection was constructed.•The detection mechanism based on (CHEF)•The sensor film is easy to applied in aqueous solution.•With high sensitivity and selectivity