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A novel low density metal-organic framework with pcu topology by dendritic ligand
Journal article   Peer reviewed

A novel low density metal-organic framework with pcu topology by dendritic ligand

Jiangtao Jia, Fuxing Sun, Qianrong Fang, Xiaoqiang Liang, Kun Cai, Zheng Bian, Huijun Zhao, Lianxun Gao and Guangshan Zhu
Chemical communications (Cambridge, England), Vol.47(32), pp.9167-9169
01/01/2011
DOI: https://doi.org/10.1039/c1cc12891d
PMID: 21755073

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
A novel low density two-fold interpenetrated MOF-5 analogue with pcu topology, JUC-100, was designed and prepared successfully. It can be regarded as MOF-5 in which half of the Zn4O(CO2)(6) units are replaced by organic 1,3,5-triphenylbenzene segments. JUC-100 exhibits H-2 uptake ability comparable to interpenetrated MOF-5, but relatively low initial isosteric heat of adsorption.

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