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A novel route to imidoylbenzotriazoles and their application for the synthesis of enaminones
Journal article   Peer reviewed

A novel route to imidoylbenzotriazoles and their application for the synthesis of enaminones

Alan R Katritzky, Amy E Hayden, Kostyantyn Kirichenko, Phillip Pelphrey and Yu Ji
Journal of organic chemistry, Vol.69(15), pp.5108-5111
23/07/2004
PMID: 15255745

Abstract

Reactions of secondary amides 2a-i with 1-chloro-1H-benzotriazole and triphenylphosphine give imidoylbenzotriazoles 3a-i. The treatment of 3a,b,e,g with silyl enol ethers 5a,b in the presence of potassium tert-butoxide provides a new general approach to enaminoketones 6a-h.

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