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A simple and efficient intramolecular 1,3-dipolar azidoalkyne cycloaddition: Synthesis of 6-perfluoroalkylated fused exo-bicyclic 1,2,3-triazolo-1,4-oxazines
Journal article   Peer reviewed

A simple and efficient intramolecular 1,3-dipolar azidoalkyne cycloaddition: Synthesis of 6-perfluoroalkylated fused exo-bicyclic 1,2,3-triazolo-1,4-oxazines

Nejib Hussein Mekni
Journal of fluorine chemistry, Vol.186, pp.97-100
01/06/2016
DOI: https://doi.org/10.1016/j.jfluchem.2016.04.010

Abstract

Chemistry Chemistry, Inorganic & Nuclear Chemistry, Organic Physical Sciences Science & Technology
The synthesis of new 6-perfluoroalkylated 1,2,3-triazolo-1,4-oxazine ethers and thioethers as fused exo-heterobicyclic compounds was achieved from terminal perfluoroalkyl oxiranes by azide ion ring opening and propargylation reactions followed by a quick and spontaneous 1,3-dipolar intramolecular cycloaddition reaction. (C) 2016 Elsevier B.V. All rights reserved.

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