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A simple route to multifunctional phosphide and amide donor sets; syntheses and structures of [{(BuPAs)-P-t(NMe2)(2)}K center dot pmdeta](2) and [{CyNAs(NMe2)(2)K}(2)](infinity)
Journal article   Peer reviewed

A simple route to multifunctional phosphide and amide donor sets; syntheses and structures of [{(BuPAs)-P-t(NMe2)(2)}K center dot pmdeta](2) and [{CyNAs(NMe2)(2)K}(2)](infinity)

M A Beswick, A Bashall, A D Hopkins, S J Kidd, Y G Lawson, M McPartlin, P R Raithby, A Rothenberger, D Stalke and D S Wright
Chemical communications (Cambridge, England), (8), pp.739-740
21/04/1999
DOI: https://doi.org/10.1039/a901222b

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
The syntheses of [(BuPAs)-P-t(NMe2)(2)K.pmedta](2) 1 and [{CyN-As(NMe2)(2)K}(2)](infinity) 2 from the reactions of [As(NMe2)(3)] with (BuPH2)-P-t and CyNH2, respectively, in the presence of potassiated bases exemplify a general approach to multifunctional secondary phosphide and amide anions containing variable sets of group 15 donor centres.

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