Abstract
A symmetric small molecule fluorescent chemosensor L based on 3-nitrobenzaldehyde was synthesized by the reaction of ethylenediamine with 3-nitrobenzaldehyde in methanol and the product gained was utilized for the detection of Fe3+ by fluorescence quenching "turn on-off " process. The fluorescence spectral data results of the probe L specified that 9.54 x 10(4) M-1 as binding constant of L for Fe3+ and the detection limits as 1.28 x 10(-6) M-1. A possible C=N isomerization and a reverse PET mechanism is proposed for the probe L detection system for Fe3+ ions constructed on the fluorescence studies and supported by the DFT calculation findings including the binding stoichiometry of the probe L with Fe3+ ion as 1:1. To demonstrate its practical utility, the sensing system was investigated for the real water sample analysis and determination of iron in iron tablet.