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A spontaneously resoluted zinc-organic framework with nonlinear optical and ferroelectric properties generated from tetrazolate-ethyl ester ligand
Journal article   Peer reviewed

A spontaneously resoluted zinc-organic framework with nonlinear optical and ferroelectric properties generated from tetrazolate-ethyl ester ligand

Xiao-Qiang Liang, Jiang-Tao Jia, Tao Wu, Dong-Ping Li, Lei Liu and Guang-Shan Zhu
CrystEngComm, Vol.12(11), pp.3499-3501
01/01/2010
DOI: https://doi.org/10.1039/C0CE00329H

Abstract

Diamonds Esters Ferroelectric materials Ferroelectricity Ligands Nonlinearity Spectra Three dimensional
A homochiral 3D diamondoid metal-organic framework [Zn2(etza)4] (1, named JUC-81, JUC = Jilin University, China, Hetza = ethyl 1H-tetrazole-5-acetate) has been prepared through spontaneous resolution. The bulk crystals have enantiomeric excess observed by vibrational circular dichroism (VCD) spectra, and also show second-order nonlinear optical effects and ferroelectric feature.

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