Abstract
This study is aimed at elucidating the nature of power-law creep, threshold stress and stress-induced diffusion in SrCo
0.8
Fe
0.2
O
3-δ
samples subjected to creep. A SrCo
0.8
Fe
0.2
O
3-δ
sample deformed in the transition from a diffusion to a power-law creep regime (900°C, 50 MPa and 15% strain) as well as an assintered sample were analysed by transmission electron microscopy and energydispersive X-ray spectroscopy. The dislocation structure has been found to be highly non-uniform with areas of high dislocation density confined only within a set of well-separated grains. The dislocation structure and distribution indicate that this compound deforms by cooperative grain-boundary sliding in the transition regime. In the grains that do deform by dislocation movement, deformation is achieved by slip through the screw {110}(110) system. A planar map of the composition distribution of constituent cations revealed large fluctuations in cation composition over distances of the order of 100-200nm, as well as a complementary distribution trend of cobalt and iron. This behaviour is found to be due to sequential stress-induced diffusion of cations, which is in accordance with the temperature dependence of the apparent activation energy. The concentration profiles perpendicular to grain boundaries clearly reveal no preferential segregation of cations at neither random nor coincident-site lattice grain boundaries, which excludes dopant segregation as the mechanism responsible for the threshold stress-like behaviour at low stresses.