A unique, rigid porous coordination polymer with 1,4,5-triazanaphthalene and mixed-valence Cu as the bridging metal

Gerard A. van Albada; Mohamed Ghazzali; Khalid Al-Farhan; Ilpo Mutikainen; Jan Reedijk

doi:10.1016/j.inoche.2010.10.012

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A unique, rigid porous coordination polymer with 1,4,5-triazanaphthalene and mixed-valence Cu as the bridging metal

Journal article

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A unique, rigid porous coordination polymer with 1,4,5-triazanaphthalene and mixed-valence Cu as the bridging metal

Gerard A. van Albada, Mohamed Ghazzali, Khalid Al-Farhan, Ilpo Mutikainen and Jan Reedijk

Inorganic chemistry communications, Vol.14(1), pp.162-165

2011

DOI: https://doi.org/10.1016/j.inoche.2010.10.012

Abstract

Copper

Metal-organic framework

Mixed-valence

A novel mixed-valence Cu(I)/Cu(II) compound with the bridging ligand 1,4,5-triazanaphthalene (tan) is reported, having the overall formula [Cu 2(tan) 4](ClO 4) 3. The synthesis, X-ray crystal structure and preliminary spectroscopic properties are presented. The coordination of Cu(I) is tetrahedral, and that of Cu(II) is square planar. The packing of the units generates a 3D network with spaces in the cavities, available for the counter anions and accessible for small solvent molecules. A novel mixed-valence porous Cu compound consisting of 1,4,5-triazanaphthalene bridging ligands is described. [Display omitted]

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Title: A unique, rigid porous coordination polymer with 1,4,5-triazanaphthalene and mixed-valence Cu as the bridging metal
Creators - without role: Gerard A. van Albada - Leiden University
Mohamed Ghazzali - King Saud University
Khalid Al-Farhan - King Saud University
Ilpo Mutikainen - University of Helsinki
Jan Reedijk - King Saud University
Publication Details: Inorganic chemistry communications, Vol.14(1), pp.162-165
Publisher: Elsevier B.V
Identifiers: 9947255908331
Academic Unit: King Saud University
Language: English
Resource Type: Journal article