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A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(IV) dicarboxylates
Journal article   Peer reviewed

A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(IV) dicarboxylates

Vincent Guillerm, Silvia Gross, Christian Serre, Thomas Devic, Matthias Bauer and Gérard Férey
Chemical communications (Cambridge, England), Vol.46(5), pp.767-769
01/01/2010
DOI: https://doi.org/10.1039/b914919h
PMID: 20087514

Abstract

Hydrocarbons, Chlorinated - chemistry Particle Size Porosity Surface Properties Temperature Zirconium - chemistry
The exchange of the monocarboxylate ligand of the zirconium methacrylate oxocluster Zr(6)O(4)(OH)(4)(OMc)(12) (OMc = CH(2)=CH(CH(3))COO) with dicarboxylic acids (trans,trans muconic acid and terephthalic acid) leads to porous zirconium dicarboxylates exhibiting the UiO-66 architecture; the mild reaction conditions allow the control of their particle size.

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