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Absolute helicity induction in three-dimensional homochiral frameworks
Journal article   Peer reviewed

Absolute helicity induction in three-dimensional homochiral frameworks

Jian Zhang, Xianhui Bu and Huabin Zhang
Chemical communications (Cambridge, England), (2), pp.206-208
01/01/2009
PMCID: PMC2790072
PMID: 19099070

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Three Co(II) isomers assembled from D-, or L-, or DL-camphorate together with achiral isonicotinate exhibit a clear relationship between chirality and helicity even though chiral molecules are not in the backbone of the helix: the absolute sense of helix made of achiral components is controlled by chains of metal and enantiopure chiral ligands running perpendicular to helix in two enantiomeric forms.

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