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Access to well-defined isolated Fe(II) centers on silica and their use in oxidation
Journal article   Peer reviewed

Access to well-defined isolated Fe(II) centers on silica and their use in oxidation

Charbel Roukoss, Steven Fiddy, Aimery de Mallmann, Nuria Rendón, Jean-Marie Basset, Emile Kuntz and Christophe Copéret
Dalton transactions : an international journal of inorganic chemistry, (47), pp.5546-5548
01/01/2007
DOI: https://doi.org/10.1039/b711015d
PMID: 18043815

Abstract

Well-defined Fe(II) isolated sites are obtained by reaction of diaryl-N,N'-diazadiene bis(neosilyl) iron (1) with an aerosil silica, SiO(2-(700)). This system can be used as a precursor for the catalytic oxidation of cyclohexene into cyclohexene oxide, cyclohexenol and cyclohexenone in the presence of H(2)O(2).

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