Abstract
In the title complex, [Cd(CH
3
COO)
2
(C
4
H
8
N
2
S)
2
], the Cd
II
cation is coordinated by three acetate O atoms and two S atoms of Diaz [Diaz = 1,3-diazinane-2-thione = 3,4,5,6-tetrahydropyrimidine-2(1
H
)-thione]. The Cd
II
coordination is augmented by one considerably longer Cd—O bond of 2.782 (3) Å to a carboxylate O atom. The resulting coordination polyhedron around the Cd
II
cations can be described as a highly distorted octahedron. The Diaz ligand and the acetate anions are linked by N—H⋯O hydrogen-bonding interactions.