Abstract
The kinetics of oxidation of kappa-carrageenan (KCAR) polysaccharide by chromic acid in aqueous perchlorate solutions have been investigated spectrophotometrically. A kinetic evidence for the formation of 1:2 intermediate complex is revealed. The oxidation product was identified by the spectral data and microanalysis as diketo-acid derivative (DKA-KCAR).
The acid-catalyzed oxidation of kappa-carrageenan (KCAR) polysaccharide as a natural polymer by chromic acid in aqueous perchloric acid at a constant ionic strength of 4.0
mol
dm
−3 have been investigated spectrophotometrically. A first-order reaction in chromic acid and a fractional-order with respect to KCAR concentrations were revealed. A kinetic evidence for the formation of 1:2 complex between chromic acid and KCAR is presented. The influence of hydrogen ion concentrations on the reaction rates showed that the oxidation process is acid-catalyzed. The kinetic parameters have been evaluated and a tentative reaction mechanism consistent with the kinetic results is discussed.