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Addition of alkynes to digermynes: experimental insight into the reaction pathway
Journal article   Peer reviewed

Addition of alkynes to digermynes: experimental insight into the reaction pathway

Nada Y Tashkandi, Laura C Pavelka, Christine A Caputo, Paul D Boyle, Philip P Power and Kim M Baines
Dalton transactions : an international journal of inorganic chemistry, Vol.45(17), pp.7226-7230
01/01/2016
PMID: 27064526

Abstract

The addition of an alkynyl cyclopropyl mechanistic probe to a digermyne did not lead to any ring-opened rearrangement products indicating that the reaction pathway does not involve any vinylic radicals or cations and providing experimental insight into the addition of alkynes to digermynes.

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