An imidazolium-functionalized mesoporous cationic metal–organic framework for cooperative CO 2 fixation into cyclic carbonate

Jun Liang; Ya-Qiang Xie; Xu-Sheng Wang; Qiang Wang; Tao-Tao Liu; Yuan-Biao Huang; Rong Cao

doi:10.1039/C7CC08630J

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An imidazolium-functionalized mesoporous cationic metal–organic framework for cooperative CO 2 fixation into cyclic carbonate

Journal article

Peer reviewed

An imidazolium-functionalized mesoporous cationic metal–organic framework for cooperative CO 2 fixation into cyclic carbonate

Jun Liang, Ya-Qiang Xie, Xu-Sheng Wang, Qiang Wang, Tao-Tao Liu, Yuan-Biao Huang and Rong Cao

Chemical communications (Cambridge, England), Vol.54(4), pp.342-345

04/01/2018

DOI: https://doi.org/10.1039/C7CC08630J

PMID: 29182177

Abstract

A mesoporous cationic Cr-MOF, termed FJI-C10 , containing imidazolium moieties, Lewis acidic Cr 3+ sites and free halogens is constructed for the first time by a topology-guided one-pot synthesis. FJI-C10 exhibits excellent performances in CO 2 adsorption (20.2 wt% at 273 K and 1 bar) and chemical fixation of CO 2 into cyclic carbonates without the use of co-catalyst under atmospheric pressure.

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Title: An imidazolium-functionalized mesoporous cationic metal–organic framework for cooperative CO 2 fixation into cyclic carbonate
Creators - without role: Jun Liang - Xiamen University
Ya-Qiang Xie - Xiamen University
Xu-Sheng Wang - Fujian Institute of Research on the Structure of Matter
Qiang Wang - Fujian Institute of Research on the Structure of Matter
Tao-Tao Liu - Fujian Institute of Research on the Structure of Matter
Yuan-Biao Huang - Fujian Institute of Research on the Structure of Matter
Rong Cao - Xiamen University
Publication Details: Chemical communications (Cambridge, England), Vol.54(4), pp.342-345
Identifiers: 9942374208331
Academic Unit: King Abdullah University of Science & Technology
Language: English
Resource Type: Journal article