An indium-based microporous metal-organic framework with unique three-way rod-shaped secondary building units for efficient methane and hydrogen storage

Hui Cui; Yingxiang Ye; Ruibiao Lin; Yanshu Shi; Zeid A. Alothman; Osamah Alduhaish; Bin Wang; Jian Zhang; Banglin Chen

doi:10.1039/d2qi01956f

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An indium-based microporous metal-organic framework with unique three-way rod-shaped secondary building units for efficient methane and hydrogen storage

Journal article

Peer reviewed

An indium-based microporous metal-organic framework with unique three-way rod-shaped secondary building units for efficient methane and hydrogen storage

Hui Cui, Yingxiang Ye, Ruibiao Lin, Yanshu Shi, Zeid A. Alothman, Osamah Alduhaish, Bin Wang, Jian Zhang and Banglin Chen

Inorganic chemistry frontiers, Vol.9(24), pp.6527-6533

06/12/2022

DOI: https://doi.org/10.1039/d2qi01956f

Abstract

Chemistry

Chemistry, Inorganic & Nuclear

Physical Sciences

Science & Technology

A novel microporous indium-based MOF material with unique 3-way rod-shaped secondary building units (SBUs), UTSA-22, was reported and exhibited high methane (CH4) and hydrogen (H-2) storage. At 298 K and 65 bar, the total CH4 volumetric uptake of UTSA-22 is 174 cm(3)(STP) cm(-3). Moreover, UTSA-22 shows a high CH4 working capacity of 146 cm(3)(STP) cm(-3) in a pressure range of 5-65 bar at 298 K. In addition, UTSA-22 shows a high H-2 gravimetric storage capacity (1.2 wt%) at 298 K and 100 bar.

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Title: An indium-based microporous metal-organic framework with unique three-way rod-shaped secondary building units for efficient methane and hydrogen storage
Creators - without role: Hui Cui - The University of Texas at San Antonio
Yingxiang Ye - University of North Texas
Ruibiao Lin - Sun Yat-sen University
Yanshu Shi - The University of Texas at San Antonio
Zeid A. Alothman - King Saud University
Osamah Alduhaish - King Saud University
Bin Wang - University of North Texas
Jian Zhang - Lawrence Berkeley National Laboratory
Banglin Chen - The University of Texas at San Antonio
Publication Details: Inorganic chemistry frontiers, Vol.9(24), pp.6527-6533
Publisher: Royal Soc Chemistry
Number of pages: 7
Grant note: DRI-KSU-572 / Ministry of Education, in Saudi Arabia 22101307 / NSFC; National Natural Science Foundation of China (NSFC) DE-AC02-05CH11231 / Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy; United States Department of Energy (DOE) AX-1730 / Welch Foundation; The Welch Foundation
Identifiers: 9948568608331
Academic Unit: King Saud University
Language: English
Resource Type: Journal article