Abstract
Structural, physical and gamma ray shielding properties of Dy3+ doped telluroborate glasses have been discussed. The molar volume of the glasses is proportional to the TeO2 content. The FTIR studies investigate the expansion of TeO2 content and the dynamic change of tetrahedral [BO4] units into trigonal [BO3] units. Using the absorption spectra, optical band gap (Eg) and Urbach's energy (ΔE) values are calculated. The molar volume of oxygen (VO) and boron‑boron separation (<dB–B>) values are increasing while there is a fall in oxygen packing density (OPD) from 0% to 40% of TeO2. The ionic nature of the present glasses is analyzed from the bonding parameter (δ), optical basicity (Λth), covalent and ionic characteristic factors. The gamma photon attenuation investigated employing GEANT4 code. The transmission factor (TF) shows that 0TBD sample (0 wt% of TeO2) has the highest TF, while the 4TBD sample (40 wt% of TeO2) has the lowest TF.
•The molar volume of oxygen increases with the TeO2 content.•All the glasses are highly ionic in nature.•More amount of TeO2 provides better photons attenuation in the glass network.•4TBD glass has the highest attenuation performance.