Abstract
Unexpected equilibrium overshoot observed during the isomerization of the title imine in [
2
H
4
]methanol is rationalised in terms of a biased kinetic deuterium isotope effect, and isomerization
via
an enamine intermediate.
- Title
- Anomalous equilibration of (Z)-N-[1-(1-naphthyl)ethylidene]isopropylamine in [2H4]methanol: a kinetic chimera involving an apparent equilibrium overshoot
- Creators - without role
- Derek R BoydSalim Al-ShowimanW. Brian JenningsValerie E Wilson
- Publication Details
- Journal of the Chemical Society, Chemical Communications, (8), pp.443-444
- Number of pages
- 2
- Identifiers
- 9952755008331
- Academic Unit
- King Saud University
- Resource Type
- Journal article