Abstract
This article describes how selectively anionic organic molecules could be removed from aqueous medium using naturally available gypsum (GS) adsorbent. Gypsum (CaSO4.2H(2)O) shows strong interactions with anionic dye molecules while it dos not show any affinity towards cationic dye molecules. We have shown the removal efficiency of gypsum taking chlorazole yellow (anionic dye) and methylene blue (cationic dye) as examples of adsorbates. The GS has been to be even more effective than activated carbon in attaining chlorazole yellow (CY) removal. Three well-known kinetic equations e.g. pseudo-first-order, pseudo-second order and intraparticle diffusion were exploited to interpret the experimental data. Results show best fitting with second order kinetic process with excellent regression coefficient (r(2) = 0.99) for the adsorption process. The equilibrium data were analyzed exploiting some adsorption isotherm models. It was apparent that the Freundlich isotherm model superbly fitted for CY dye adsorption process. And the maximum adsorption capacity, Q(m), was obtained as 12.85 mg g(-1) at room temperature. The negative values of Gibb's free energy change (Delta G(o)) suggests that the CY dye molecule adsorption process is spontaneous in nature. Moreover, negative enthalpy change (Delta H-o) indicates the exothermic nature of the adsorption process. The outcome could be exploited where anionic organic molecules are required to be separated, selectively.