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Aqua{6,6-dimethyl-2,2 '-[o-phenylenebis(nitrilomethylidyne)]diphenolato-kappa(4) O,N,N ',O '}zinc(II) chloroform solvate
Journal article

Aqua{6,6-dimethyl-2,2 '-[o-phenylenebis(nitrilomethylidyne)]diphenolato-kappa(4) O,N,N ',O '}zinc(II) chloroform solvate

Naser Eltaher Eltayeb, Siang Guan Teoh, Suchada Chantrapromma, Hoong-Kun Fun and Kamarulazizi Ibrahim
Acta crystallographica. Section E, Structure reports online, Vol.63(9), pp.M2294-U434
09/2007
DOI: https://doi.org/10.1107/S1600536807038536

Abstract

Crystallography Physical Sciences Science & Technology
In the title compound, [Zn(C22H18N2O2)(H2O)] center dot CHCl3, the Zn-II centre is in a five-coordinate square-pyramidal N2O3 environment, with the N2O2 set of atoms from the Schiff base ligand forming the basal plane; the water molecule occupies the apical position. Intermolecular O-H center dot center dot center dot O hydrogen bonds and weak C-H center dot center dot center dot O interactions link the molecules into a chain along [100]. The chains form sheets parallel to the ac plane.

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