Asymmetric induction in homochiral MOFs: from interweaving double helices to single helices

Xin Wu; Hua-Bin Zhang; Zhong-Xuan Xu; Jian Zhang

doi:10.1039/c5cc06501a

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Asymmetric induction in homochiral MOFs: from interweaving double helices to single helices

Journal article

Peer reviewed

Asymmetric induction in homochiral MOFs: from interweaving double helices to single helices

Xin Wu, Hua-Bin Zhang, Zhong-Xuan Xu and Jian Zhang

Chemical communications (Cambridge, England), Vol.51(91), pp.16331-16333

01/01/2015

DOI: https://doi.org/10.1039/c5cc06501a

PMID: 26400234

Abstract

Chemistry

Chemistry, Multidisciplinary

Physical Sciences

Science & Technology

Two three-dimensional (3D) homochiral metal-organic frameworks, integrating double helical chains based on enantiopure ligands and single helical structures braided by 4,4'-bipyridine (bipy) and cadmium clusters, have been synthesized successfully, as a result of complete asymmetric induction between the two types of helix.

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Title: Asymmetric induction in homochiral MOFs: from interweaving double helices to single helices
Creators - without role: Xin Wu - Fujian Institute of Research on the Structure of Matter
Hua-Bin Zhang - Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
Zhong-Xuan Xu - Fujian Institute of Research on the Structure of Matter
Jian Zhang - Fujian Institute of Research on the Structure of Matter
Publication Details: Chemical communications (Cambridge, England), Vol.51(91), pp.16331-16333
Publisher: Royal Soc Chemistry
Number of pages: 3
Grant note: 2012CB821705 / 973 program; National Basic Research Program of China 21221001; 21425102 / NSFC; National Natural Science Foundation of China (NSFC)
Identifiers: 9942919608331
Academic Unit: King Abdullah University of Science & Technology
Language: English
Resource Type: Journal article