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B(C6F5)(3) promoted cyclisation of internal propargyl esters: structural characterisation of 1,3-dioxolium compounds
Journal article   Peer reviewed

B(C6F5)(3) promoted cyclisation of internal propargyl esters: structural characterisation of 1,3-dioxolium compounds

Max M. Hansmann, Rebecca L. Melen, Frank Rominger, A. Stephen K. Hashmi and Douglas W. Stephan
Chemical communications (Cambridge, England), Vol.50(55), pp.7243-7245
01/01/2014
PMID: 24817134

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
The reactions of internal propargyl esters with B(C6F5)(3) provide access to stable zwitterionic 1,3-dioxolium compounds which are characterised by X-ray diffraction. These 6 pi-electron systems show no significant aromatic stabilisation.

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