Abstract
Poly(ethylene-co-vinyl acetate) (EVA)/cellulose composite membranes were prepared and their vapor permeation characteristics were studied. Two types of EVA [having vinyl acetate contents of 18% (EVA18) and of 40% (EVA40), respectively] were used for the composite fabrication. Cellulose, isolated from banana waste fibers, was used as the filler. It was observed that the EVA40 composites were more permeating than were the EVA18 composites. This observation is explained on the basis of more amorphous nature of EVA40 as compared to EVA18. The extent of vapor permeation decreased with increase in the cellulose content in the composites. The presence of voids in the polymer membranes that were designed to possess controlled behavior for the permeation was confirmed using scanning electron microscopic images to complement the observations made during the permeation studies. The influence of molecular weight, molar size, and polarity of the penetrants, on the permeation process, was also considered. The permeability of the membrane samples was calculated and the values obtained were compared with the theoretical values provided by using the modified Neilson permeability equation. POLYM. ENG. SCI., 2012.(C) 2012 Society of Plastics Engineers