Benzotriazol-1-ylmethyl isocyanide, a new synthon for CHNC transfer. Syntheses of α-hydroxyaldehydes, 4-ethoxy-2-oxazolines and oxazoles

Alan R. Katritzky; Ya-Xiong Chen; Konstantina Yannakopoulou; Ping Lue

doi:10.1016/S0040-4039(00)70643-5

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Benzotriazol-1-ylmethyl isocyanide, a new synthon for CHNC transfer. Syntheses of α-hydroxyaldehydes, 4-ethoxy-2-oxazolines and oxazoles

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Benzotriazol-1-ylmethyl isocyanide, a new synthon for CHNC transfer. Syntheses of α-hydroxyaldehydes, 4-ethoxy-2-oxazolines and oxazoles

Alan R. Katritzky, Ya-Xiong Chen, Konstantina Yannakopoulou and Ping Lue

Tetrahedron letters, Vol.30(48), pp.6657-6660

1989

DOI: https://doi.org/10.1016/S0040-4039(00)70643-5

Abstract

Readily prepared benzotriazol-1-ylmethyl isocyanide (BetMIC) reacts under mild conditions with ketones and aldehydes, to afford oxazolines (convertible into α-hydroxyaldehydes) and oxazoles, respectively. Graphic

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Title: Benzotriazol-1-ylmethyl isocyanide, a new synthon for CHNC transfer. Syntheses of α-hydroxyaldehydes, 4-ethoxy-2-oxazolines and oxazoles
Creators - without role: Alan R. Katritzky - University of Florida
Ya-Xiong Chen
Konstantina Yannakopoulou - University of Florida
Ping Lue - University of Florida
Publication Details: Tetrahedron letters, Vol.30(48), pp.6657-6660
Publisher: Elsevier Ltd
Identifiers: 9935296308331
Academic Unit: King Abdulaziz University
Language: English
Resource Type: Journal article