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Bifunctional covalent organic frameworks with two dimensional organocatalytic micropores
Journal article   Peer reviewed

Bifunctional covalent organic frameworks with two dimensional organocatalytic micropores

Digambar Balaji Shinde, Sharath Kandambeth, Pradip Pachfule, Raya Rahul Kumar and Rahul Banerjee
Chemical communications (Cambridge, England), Vol.51(2), pp.310-313
07/01/2015
DOI: https://doi.org/10.1039/c4cc07104b
PMID: 25408225

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
We report the successful incorporation of bifunctional (acid/base) catalytic sites in the crystalline organocatalytic porous COF (2,3-DhaTph). Due to the presence of acidic (catachol) and basic (porphyrin) sites, 2,3-DhaTph shows significant selectivity, reusability, and excellent ability to perform the cascade reaction.

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