Abstract
In the title compound, [CuBr(C
13
H
12
N
2
S)
2
]·H
2
O, the Cu
I
atom adopts a slightly distorted trigonal-planar coordination arising from two S atoms of two diphenylthiourea ligands and a bromide ion. There are two intramolecular N—H⋯Br hydrogen bonds completing twisted six-membered rings with
R
(6) motifs. The dihedral angles between the aromatic rings in the ligands are 62.11 (13) and 85.73 (13)°. In the crystal, components are linked by N—H⋯O, O—H⋯S and O—H⋯π interactions. There also exist π–π interactions with a distance of 3.876 (2) Å between the centroids of benzene rings of two different ligands. Together, the intermolecular interactions lead to a three-dimensional network.