Abstract
In the current work, good quality bulk size (∼32 mm × 23 mm × 10 mm) single crystals of HCl added l-alanine with well-defined morphology are successfully grown using slow evaporation technique. Crystal structure and other structural parameters were evaluated from X-ray diffraction data. Vibrational assessment of the grown crystal was done by FT-Raman analysis. The presence of chlorine and good quality of the grown crystal was confirmed by SEM/EDX analysis. Solid state UV–Vis–NIR diffused reflectance was measured and direct and indirect optical band gap was calculated using Kubelka-Munk relation and found to be 5.64 and 5 eV respectively. Dielectric measurement was carried out in high frequency range. Third order nonlinear optical susceptibility value was found to be enhanced from 1.91 × 10−6 (pure) to 8.6 × 10−6 esu (LAHCl). Good thermal stability of grown crystals was confirmed from DSC analysis. The enhancement in mechanical strength and crystalline perfection was also observed.
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•Bulk size (32 mm × 23 mm × 10 mm), good crystalline perfection HCl added l-alanine monocrystal is grown.•The shift in X-ray diffraction and vibrational peaks confirms the interaction of HCl.•The high optical transparency and band gap confirms its application in optoelectronic devices.•Third order NLO properties are found to be enhanced in HCl added l-alanine crystals.•The mechanical strength of the grown crystals is found to be enhanced due HCl addition.