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C-H activations on a 1H-1,4-benzodiazepin-2(3H)-one template
Journal article   Peer reviewed

C-H activations on a 1H-1,4-benzodiazepin-2(3H)-one template

John Spencer, Babur Z. Chowdhry, Anthony I. Mallet, Rajendra P. Rathnam, Trushar Adatia, Alan Bashall and Frank Rominger
Tetrahedron, Vol.64(26), pp.6082-6089
23/06/2008
DOI: https://doi.org/10.1016/j.tet.2008.01.059

Abstract

Chemistry Chemistry, Organic Physical Sciences Science & Technology
Air stable benzodiazepine containing palladacycles were synthesized by a C-H activation reaction and studied by mass spectrometry and X-ray crystallography. Catalytic C-H functionalizations of 1-methyl-5-phenyl-1H-1,4-benzodiazepin-2(3H)-one with diphenyliodonium hexafluorophosphate led to a mixture, which included the starting material and the expected product 1-methyl-5-(2'-biphenyl)-1H-1,4-benzodiazepin-2(3H)-one. (C) 2008 Elsevier Ltd. All rights reserved.

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