Carbonization of covalent triazine-based frameworks via ionic liquid induction

Jiangtao Jia; Zhijie Chen; Youssef Belmabkhout; Karim Adil; Prashant M. Bhatt; Vera A. Solovyeva; Osama Shekhah; Mohamed Eddaoudi

doi:10.1039/c8ta05583a

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Carbonization of covalent triazine-based frameworks via ionic liquid induction

Journal article

Peer reviewed

Carbonization of covalent triazine-based frameworks via ionic liquid induction

Jiangtao Jia, Zhijie Chen, Youssef Belmabkhout, Karim Adil, Prashant M. Bhatt, Vera A. Solovyeva, Osama Shekhah and Mohamed Eddaoudi

Journal of materials chemistry. A, Materials for energy and sustainability, Vol.6(32), pp.15564-15568

2018

DOI: https://doi.org/10.1039/c8ta05583a

Abstract

Chemistry

Chemistry, Physical

Energy & Fuels

Materials Science

Materials Science, Multidisciplinary

Physical Sciences

Science & Technology

Technology

A series of porous organic polymers (POPs) were synthesized using tetrahedral 1,3,5,7-tetracyanoadamantane as the main building block. The POP frameworks in the presence of different amounts of molten ZnCl2 as an ionic liquid were allowed to alter/enhance the Brunauer-Emmett-Teller (BET) surface areas of the POPs in the range from 760 to 1560 m(2) g(-1). The mechanism of the carbonization was unveiled by IR, EA and solid-state NMR; which is in situ ionic liquid induced polymerization and carbonization of the POPs.

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Title: Carbonization of covalent triazine-based frameworks via ionic liquid induction
Creators - without role: Jiangtao Jia - King Abdullah University of Science and Technology
Zhijie Chen - King Abdullah University of Science and Technology
Youssef Belmabkhout - King Abdullah University of Science and Technology
Karim Adil - King Abdullah University of Science and Technology
Prashant M. Bhatt - King Abdullah University of Science and Technology
Vera A. Solovyeva - King Abdullah University of Science and Technology
Osama Shekhah - King Abdullah University of Science and Technology
Mohamed Eddaoudi - King Abdullah University of Science and Technology
Publication Details: Journal of materials chemistry. A, Materials for energy and sustainability, Vol.6(32), pp.15564-15568
Publisher: Royal Soc Chemistry
Number of pages: 5
Identifiers: 9941192308331
Academic Unit: King Abdullah University of Science & Technology
Language: English
Resource Type: Journal article