Sign in
Back
Catalytic Intermolecular Cross-Couplings of Azides and LUMO-Activated Unsaturated Acyl Azoliums
Journal article   Peer reviewed

Catalytic Intermolecular Cross-Couplings of Azides and LUMO-Activated Unsaturated Acyl Azoliums

Wenjun Li, Manjaly J. Ajitha, Ming Lang, Kuo-Wei Huang and Jian Wang
ACS catalysis, Vol.7(3), pp.2139-2144
03/03/2017
DOI: https://doi.org/10.1021/acscatal.6b03674

Abstract

Chemistry Chemistry, Physical Physical Sciences Science & Technology
An example for the catalytic synthesis of densely functionalized 1,2,3-triazoles through a LUMO activation mode has been developed. The protocol is enabled by intermolecular cross coupling reactions of azides with in situ-generated alpha,beta-unsaturated acyl azoliums. High yields and broad scope as well as the investigation of reaction mechanism are reported.

Metrics

1 Record Views

Details