Abstract
Concentrations of dissolved iron (DFe) and Fe-binding ligands were determined in the tropical Northeast Atlantic Ocean (12–30°N, 21–29°W) as part of the UK-SOLAS (Surface Ocean Lower Atmosphere Study) cruise Poseidon 332 (P332) in January–February 2006. The surface water DFe concentrations varied between 0.1 and 0.4 nM with an average of 0.22
±
0.05 nM (
n
=
159). The surface water concentrations of total Fe-binding ligands varied between 0.82 and 1.46 nM with an average of 1.11
±
0.14 nM (
n
=
33). The concentration of uncomplexed Fe-binding ligands varied between 0.64 and 1.35 nM with an average of 0.90
±
0.14 nM (
n
=
33). Thus, on average 81% of the total Fe-binding ligand concentration was uncomplexed. The average logarithmic conditional stability constant of the pool of Fe-binding ligands was 22.85
±
0.38 with respect to Fe
3+ (
n
=
33). A transect (12°N, 26°W to 16°N, 25.3°W) was sailed during a small Saharan dust event and repeated a week later. Following the dust event, the concentration of DFe increased from 0.20
±
0.026 nM (
n
=
125) to 0.25
±
0.028 (
n
=
17) and the concentration of free Fe-binding ligands decreased from 1.15
±
0.15 (
n
=
4) to 0.89
±
0.10 (
n
=
4) nM. Furthermore, the logarithmic stability constants of the Fe-binding ligands south of the Cape Verde islands were distinctively lower than north of the islands. The absence of a change in the logarithmic stability constant after the dust event south of the Cape Verde islands suggests that there was no significant atmospheric input of new Fe-binding ligands during this dust event.