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Charged cyclometalated iridium(III) complexes that have large electrochemical gap
Journal article   Peer reviewed

Charged cyclometalated iridium(III) complexes that have large electrochemical gap

Nail M. Shavaleev, Rosario Scopelliti, Etienne Baranoff, Michael Graetzel and Mohammad K. Nazeeruddin
INORGANICA CHIMICA ACTA, Vol.383, pp.316-319
30/03/2012
DOI: https://doi.org/10.1016/j.ica.2011.10.052

Abstract

Chemistry Chemistry, Inorganic & Nuclear Physical Sciences Science & Technology
Bis-cyclometalated cationic Ir(III) diimine complexes [Ir((CN)-N-Lambda)2((NN)-N-Lambda)](PF6) with 1-phenylpyrazoles ((CN)-N-Lambda) and 1-(4'-tert-butyl-2'-pyridyl) pyrazole ((NN)-N-Lambda) are white solids that have absorption onset below 425 nm and electrochemical gap of up to 3.5 V. (C) 2011 Elsevier B. V. All rights reserved.

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