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ChemInform Abstract: Hydrogenolysis and Homologation of Linear and Branched Pentenes on Ru/SiO2 Catalysts: Implication in the Mechanism of C‐C Bond Formation and Cleavage on Metal Surfaces
Journal article

ChemInform Abstract: Hydrogenolysis and Homologation of Linear and Branched Pentenes on Ru/SiO2 Catalysts: Implication in the Mechanism of C‐C Bond Formation and Cleavage on Metal Surfaces

E. Rodriguez, M. Leconte, J. M. Basset, K. Tanaka and K.‐I. Tanaka
ChemInform, Vol.19(15), pp.no-no
12/04/1988
DOI: https://doi.org/10.1002/chin.198815085

Abstract

alkylation, arylation, dealkylation, dearylation, C‐acylation, olefination catalysis, phase‐transfer catalysis cleavage reactions, decomposition reactions, pyrolysis
Hydrogenolysis and homologation of pentenes such as 1‐pentene to butenes, methane (5%), and hexenes take place simultaneously and at the same rate over a Ru/SiO2 catalyst at 110 °C. Unlabeled 1‐butene and labeled hexenes are obtained from (1‐13C)‐1‐pentene.

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